Synthesis and structure of {η3-MeSi(CH2SPh)3}Cr(CO)3:: how long can a Cr(0)-S(thioether) bond length be?

被引：16

作者：

Blackwell, WC

Bunich, D

Concolino, TE

Rheingold, AL ^{[1
]}

Rabinovich, D

机构：

[1] Univ Delaware, Dept Chem & Biochem, Newark, DE 19716 USA

[2] Univ N Carolina, Dept Chem, Charlotte, NC 28223 USA

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2000年 / 3卷 / 06期

关键词：

chromium complexes; thioether complexes; crystal structures; tris(thioether) silane;

D O I：

10.1016/S1387-7003(00)00079-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new tridentate thioether ligand MeSi(CH2SPh)(3) has been prepared in good yield and its first transition metal derivative, the octahedral chromium tricarbonyl complex {eta(3)-MeSi(CH2SPh)(3)}Cr(CO)(3), has been synthesized and fully characterized. in agreement with the reduced basicity of arylthioethers and the expected lability of their metal complexes, the new complex exhibits the longest Cr(0)-S(thioether) bond distances observed to date. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

收藏

页码：325 / 327

页数：3

相关论文

共 37 条

[1] CIS-1,4-CYCLOHEXADIENEBISEPISULPHIDE COMPLEXES OF CHROMIUM, MOLYBDENUM AND TUNGSTEN CARBONYLS - THE X-RAY CRYSTAL-STRUCTURE OF [CR(CO)4(CHSCHCH2CHSCHCH2)] [J].

ABEL, EW ;

COOLEY, NA ;

KITE, K ;

ORRELL, KG ;

SIK, V ;

HURSTHOUSE, MB ;

DAWES, HM .

POLYHEDRON, 1989, 8 (07) :887-891

[2] FURTHER INVESTIGATION OF THE NATURE OF THE C-LI BOND - STRUCTURES OF A PHENYLTHIOMETHYLLITHIUM COMPLEX AND OF A METHYLTHIOMETHYLLITHIUM COMPLEX [J].

AMSTUTZ, R ;

LAUBE, T ;

SCHWEIZER, WB ;

SEEBACH, D ;

DUNITZ, JD .

HELVETICA CHIMICA ACTA, 1984, 67 (01) :224-236

[3] ORGANIC SYNTHESES WITH TRANSITION-METAL COMPLEXES .39. THIOKETENE AND SELENOKETENE IMINES FROM THIOCARBENE AND SELENOCARBENE COMPLEXES OF CHROMIUM, TUNGSTEN, MANGANESE AND ISOCYANIDES [J].

AUMANN, R ;

SCHRODER, J ;

KRUGER, C ;

GODDARD, R .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 378 (02) :185-197

[4] CRYSTAL AND MOLECULAR-STRUCTURE OF TETRACARBONYL(3,6-DITHIAOCTANE)-CHROMIUM(0) - EVIDENCE FOR PI-BONDING BY A THIOETHER LIGAND [J].

BAKER, EN ;

LARSEN, NG .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1976, (18) :1769-1773

[5] CHEMISTRY OF THIOETHER MACROCYCLIC COMPLEXES [J].

Blake, Alexander J. ;

Schroeder, Martin .

ADVANCES IN INORGANIC CHEMISTRY <D>, 1990, 35 :1-80

[6]

COOPER SR, 1990, STRUCT BOND, V72, P1

[7] PHENYLTHIOMETHYLLITHIUM AND BIS(PHENYLTHIO)METHYLLITHIUM [J].

COREY, EJ ;

SEEBACH, D .

JOURNAL OF ORGANIC CHEMISTRY, 1966, 31 (12) :4097-&

[8] MOLECULAR STRUCTURE AND BONDING IN DIETHYLENETRIAMINECHROMIUM TRICARBONYL - CR(0) AND APPROXIMATE MN(0) RADII [J].

COTTON, FA ;

RICHARDS.DC .

INORGANIC CHEMISTRY, 1966, 5 (11) :1851-&

[9]

DOTZ KH, 1988, J ORGANOMET CHEM, V355, P177

[10] REVERSAL OF THE STEREOSELECTIVITY OF [4 + 2]-CYCLOADDITIONS BY COORDINATION OF THE HETERODIENOPHILE TO A TRANSITION-METAL FRAGMENT [J].

FISCHER, H ;

TREIER, K ;

GERBING, U ;

HOFMANN, J .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (10) :667-668

← 1 2 3 4 →