Synthesis and mechanical properties of Nb2AlC and (Ti,Nb)2AlC

In this paper we report on the fabrication and characterization of Nb2AlC (actual Nb:Al:C ratios: 52.5 +/- 0.5, 24.0 +/- 0.2 and 23.5 +/- 0.5 at.%, respectively) and (Ti,Nb)(2)AlC (actual Ti:Nb:Al:C atomic ratios: 24.4 +/- 0.5, 27.3 +/- 0.5, 24.0 +/- 0.3 and 24.4 +/- 0.5 at.%, respectively). Polycrystalline, fully dense, predominantly single-phase samples of Nb2AlC, (average grain size approximate to 14 +/- 2 mum) were fabricated by reactive hot isostatic pressing of Nb, graphite, and Al4C3 at 1600degreesC for 8 h and 100 MPa. The identical procedure resulted in predominantly single-phase samples-with an average grain size of 45 mum-of (Ti,Nb)(2)AlC. To obtain finer-grained (approximate to15+/-3 mum) samples of the solid solution the powder mixtures were hot pressed at 1450degreesC for 24 h. The a and c lattice parameters of Al-poor Nb2AlC samples are, respectively, 3.107+/-0.001 and 13.888+/-0.001 Angstrom; the corresponding values for the solid solution are 3.077+/-0.001 and 13.790+/-0.001 Angstrom. Since the hardness of the solid solution (5.8 GPa) is in between those of Nb2AlC (6.1 GPa) and Ti2AlC, and, at comparable grain sizes, Nb2AlC is stronger, we conclude that no solid solution strengthening occurs in this system. All samples explored in this work are quite damage tolerant and thermal shock resistant. A 300 N Vickers indentation in a 1.5 mm thick, four-point bend bar decreases the strengths by anywhere from 25 to 50% depending on grain size. Quenching in water from 1200 degreesC reduces the four-point flexural strength by 40 to 70%; i.e., it is not catastrophic. Both compositions are strain rate sensitive. Like Ti3SiC2 and ice, and for the same reasons, the compressive stress of the Nb2AlC sample decrease with decreasing strain rate. In contradistinction, and for reasons that are not understood, the strengths of the (Ti,Nb)(2)AlC samples decrease with increasing strain rates. The grain growth kinetics of Nb2AlC are quite sluggish; no appreciable grain growth was observed even after annealing at 1600degreesC for 16 h. (C) 2002 Elsevier Science B.V. All rights reserved.