2-aryl-5-epoxynitrile anion cyclizations:: Total syntheses of (±)-α-cuparenone and (±)-epilaurene

被引：6

作者：

Avila-Zárraga, JG

Maldonado, LA

机构：

[1] Natl Autonomous Univ Mexico, Inst Quim, Mexico City 04510, DF, Mexico

[2] Natl Autonomous Univ Mexico, Div Estudios Posgrado, Mexico City 04510, DF, Mexico

来源：

CHEMISTRY LETTERS | 2000年 / 05期

关键词：

D O I：

10.1246/cl.2000.512

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Total syntheses of the cyclopentane sesquiterpenes of the title using an epoxynitrile anion cyclization reaction as key step, are described. The preferential formation of the cyclopentane ring from a terminal disubstituted 5-epoxynitrile (e.g. 2b) had not previously been observed. The 2-aryl substituent is reasonably assumed to be responsible for this divergence.

引用

页码：512 / 513

页数：2

共 13 条

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