Water-gas shift reaction catalyzed by mononuclear ruthenium complexes containing bipyridine and phenanthroline derivatives

被引：12

作者：

Aguirre, P

Moya, SA ^{[1
]}

Sariego, R

Le Bozec, H

Pardey, AJ

机构：

[1] Univ Chile, Fac Ciencias Quim & Farmaceut, Dept Quim Inorgan & Analit, Casilla 233, Santiago, Chile

[2] Univ Santiago Chile, Fac Quim & Biol, Dept Quim Aplicada, Santiago, Chile

[3] Univ Rennes 1, CNRS, UMR6509, Lab Chim Coordinat & Catalyse, F-35042 Rennes, France

[4] Cent Univ Venezuela, Fac Ciencias, Escuela Quim, Caracas, Venezuela

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2002年 / 16卷 / 10期

关键词：

water-gas shift reaction; catalysis; ruthenium complexes; carbon monoxide;

D O I：

10.1002/aoc.353

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Ruthenium complexes of the type [RuL(CO)(2)Cl-2], [RuL2Cl2], [RuL2(CO)(H2O)](PF6)(2), [RuL2Cl](2)(PF6)(2), [RuL2(CO)Cl](PF6), and [RuL2(CO3)].3H(2)O (where L is a bipyridine or phenanthroline derivative) dissolved in aqueous 2-ethoxyethanol, and in a basic medium of KOH, triethylamine, or trimethylamine, catalyze the water-gas shift reaction under mild conditions (P-CO = 0.9 atm at 100degreesC). Copyright (C) 2002 John Wiley Sons, Ltd.

引用

页码：597 / 600

页数：4

共 15 条

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