Theoretical investigation of the pathway for reductive cleavage of dinitrogen by a vanadium diamidoamine complex

被引：30

作者：

Bates, VME

Clentsmith, GKB

Cloke, FGN

Green, JC

Jenkin, HDL

机构：

[1] Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England

[2] Univ Sussex, Sch Chem Phys & Environm Sci, Chem Lab, Brighton BN1 9QJ, E Sussex, England

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 11期

关键词：

D O I：

10.1039/b002534h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Density functional calculations show that [HN(CH2CH2NH)(2)V] will bind N-2 in a sideways fashion; further reaction with another molecule of [HN(CH2CH2NH)(2)V] leads to reductive cleavage of the N-2 moiety to form a bridged nitrido dimer, [HN(CH2CH2NH)(2)V(mu-N)](2); this study provides a model for the formation of [RN(CH2CH2NR)(2)V(mu-N)](2) (R = SiMe3) by reduction of [RN(CH2CH2NR)(2)V(mu-Cl)](2) under an N-2 atmosphere.

引用

页码：927 / 928

页数：2

共 11 条

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