A critique of some recent suggestions to correct the Kirkwood-Buff integrals

被引:15
作者
Ben-Naim, A. [1 ]
机构
[1] Hebrew Univ Jerusalem, Dept Phys Chem, IL-91904 Jerusalem, Israel
关键词
D O I
10.1021/jp0625356
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This article is a thorough critique of some recent publications by Matteoli, Lepori, Ruckenstein and others who suggested a correction to the Kirkwood-Buff integrals to obtain "better" information on the molecular interactions. It is shown that the suggested "corrected" Kirkwood-Buff integrals are, in fact, less informative than the original integrals. A detailed and critical examination of the arguments that led to the suggested correction reveals some serious flaws. Therefore, it is argued that the corrected Kirkwood-Buff integrals should be "recorrected" to restore their original definition and meaning.
引用
收藏
页码:2896 / 2902
页数:7
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