The preparation of high activity DMFC Pt/C electrocatalysts using a pre-precipitation method

被引：28

作者：

Liu, Changpeng

Xue, Xinzhong

Lu, Tianhong

Xing, Wei ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Peoples R China

[2] Nanjing Normal Univ, Coll Chem & Environm Sci, Nanjing 210097, Peoples R China

来源：

JOURNAL OF POWER SOURCES | 2006年 / 161卷 / 01期

基金：

中国国家自然科学基金;

关键词：

direct methanol fuel cell; Pt/C catalyst; preparation method; oxygen reduction;

D O I：

10.1016/j.jpowsour.2006.03.084

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

It is suggested that a Pt/C cathodic catalyst for the direct methanol fuel cell (DMFC) can be prepared with a pre-precipitation method, in which, H2PtCl6 is precipitated onto the carbon black as (NH4)(2)PtCl6 before H2PtCl6 is reduced to Pt. The electrocatalytic activity of this Pt/C-A catalyst for oxygen reduction is excellent because the Pt/C catalyst prepared with this pre-precipitation method possesses a small average particle size, low relative crystalinity and a large electrochemically active surface area. In addition, the pre-precipitation method is simple and economical and it can be used to prepare a Pt/C catalyst on a large scale. (c) 2006 Published by Elsevier B.V.

引用

页码：68 / 73

页数：6

共 28 条

[1] Formation of carbon supported PtRu alloys: an XRD analysis [J].