Hydrothermal preparation of octadecahedron Fe3O4 thin film for use in an electrochemical supercapacitor

被引:140
作者
Chen, Jie [1 ]
Huang, Kelong [1 ]
Liu, Suqin [1 ]
机构
[1] Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China
关键词
Fe3O4; film; Hydrothermal method; Electrochemical property; Supercapacitor; IRON-OXIDE; MAGNETITE; GROWTH;
D O I
10.1016/j.electacta.2009.04.017
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A Fe3O4 film with regularly edge-affected cubic (octadecahedron) morphology was successfully prepared on stainless steel foil by a simple and benign hydrothermal process. The potential for the use of the film in a supercapacitor was tested by investigating the electrochemical behavior of the Fe3O4 film using cyclic voltammetry (CV) and galvanostatic charge/discharge tests. The Fe3O4 film showed a CV indicative of a typical pseudocapactive behavior in 1 mol L-1 Na2SO3 solution. Furthermore, this film exhibited a specific capacitance of 118.2 F g(-1) at the current of 6 mA between -1 and 0.1 V with a capacity retention of 88.75% after 500 cycles. (C) 2009 Published by Elsevier Ltd.
引用
收藏
页码:1 / 5
页数:5
相关论文
共 17 条
[1]  
[Anonymous], KRISTALLOGRAFIYA
[2]   A hybrid Fe3O4-MnO2 capacitor in mild aqueous electrolyte [J].
Brousse, T ;
Belanger, D .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2003, 6 (11) :A244-A248
[3]   HYDROTHERMAL DEPOSITION OF MAGNETITE (FE3O4) THIN-FILMS [J].
CHEN, QW ;
QIAN, YT ;
CHEN, ZY ;
XIE, Y ;
ZHOU, GE ;
ZHANG, YH .
MATERIALS LETTERS, 1995, 24 (1-3) :85-87
[4]  
EERENSTEIN W, 2003, J MAGN MAGN MATER, V73, P258
[5]   Atomistic simulation of the surface energy of spinel MgAl2O4 [J].
Fang, CM ;
Parker, SC ;
de With, G .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2000, 83 (08) :2082-2084
[6]   Size-controlled growth of Co3O4 nanocubes [J].
Feng, J ;
Zeng, HC .
CHEMISTRY OF MATERIALS, 2003, 15 (14) :2829-2835
[7]   Growth of submicrometer-scale rectangular parallelepiped rutile TiO2 films in aqueous TiCl3 solutions under hydrothermal conditions [J].
Hosono, E ;
Fujihara, S ;
Kakiuchi, K ;
Imai, H .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (25) :7790-7791
[8]   Electrochemical supercapacitor material based on manganese oxide: preparation and characterization [J].
Jiang, JH ;
Kucernak, A .
ELECTROCHIMICA ACTA, 2002, 47 (15) :2381-2386
[9]  
Krause M.K., 2002, J MAGN MAGN MATER, V242, P662
[10]  
KRAUSE MK, 2002, J MAGN MAGN MATER, V1097, P242