Adsorbate-adsorbate interaction mediated by substrate lattice

被引：10

作者：

Brako, R ^{[1
]}

Sokcevic, D ^{[1
]}

机构：

[1] Rudjer Boskovic Inst, Div Theoret Phys, Zagreb 10001, Croatia

来源：

SURFACE SCIENCE | 2000年 / 454卷 / 454期

关键词：

carbon monoxide; chemisorption; copper; low index single crystal surfaces; nickel; platinum; surface relaxation and reconstruction; surface stress;

D O I：

10.1016/S0039-6028(00)00070-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We calculate the adsorbate-induced surface stress and the adsorbate-adsorbate interaction assuming that the adsorbate exerts a force on surrounding substrate atoms. The most prominent result is a non-monotonic distance dependence of the interaction energies, in agreement with available data for CO chemisorption on several noble-metal surfaces. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：623 / 627

页数：5

共 22 条

[1] THE ORIGIN OF FORCE-CONSTANT SOFTENING ON THE CLOSE-PACKED NOBLE-METAL SURFACES [J].

BORTOLANI, V ;

ERCOLESSI, F ;

TOSATTI, E ;

FRANCHINI, A ;

SANTORO, G .

EUROPHYSICS LETTERS, 1990, 12 (02) :149-154

[2] SURFACE PHONONS ON THE PT(111) SURFACE - A COMPARISON OF HE-SCATTERING EXPERIMENTS WITH LATTICE-DYNAMICAL CALCULATIONS [J].

BORTOLANI, V ;

FRANCHINI, A ;

SANTORO, G ;

TOENNIES, JP ;

WOLL, C ;

ZHANG, G .

PHYSICAL REVIEW B, 1989, 40 (06) :3524-3545

[3] Adsorbate interactions of CO chemisorbed on Pt(111) [J].

Brako, R ;

Sokcevic, D .

SURFACE SCIENCE, 1998, 401 (01) :L388-L394

[4] A FT-RAIRS INVESTIGATION OF THE NATURE OF THE 3-FOLD BRIDGE-CO SPECIES ON NI(111) [J].

CHEN, JG ;

ERLEY, W ;

IBACH, H .

SURFACE SCIENCE, 1989, 223 (1-2) :L891-L896

[5] CARBON-MONOXIDE ON NI(111) - ADSORPTION-ISOTHERMS AND INTERMOLECULAR INTERACTIONS [J].

GIJZEMAN, OLJ ;

VANZANDVOORT, MMJ ;

LABOHM, F ;

VLIEGENTHART, JA ;

JONGERT, G .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1984, 80 :771-781

[6] ADSORBATE-INDUCED SURFACE STRESS - CO ON NI(100) AND NI(111) [J].

GROSSMANN, A ;

ERLEY, W ;

IBACH, H .

SURFACE SCIENCE, 1994, 313 (1-2) :209-214

[7] Determination of adsorption sites of pure and coadsorbed CO on Ni(111) by high resolution X-ray photoelectron spectroscopy [J].

Held, G ;

Schuler, J ;

Sklarek, V ;

Steinruck, HP .

SURFACE SCIENCE, 1998, 398 (1-2) :154-171

[8] PT(111) NETWORK RECONSTRUCTION - STRUCTURE, GROWTH AND DECAY [J].

HOHAGE, M ;

MICHELY, T ;

COMSA, G .

SURFACE SCIENCE, 1995, 337 (03) :249-267

[9] The role of surface stress in reconstruction, epitaxial growth and stabilization of mesoscopic structures [J].

Ibach, H .

SURFACE SCIENCE REPORTS, 1997, 29 (5-6) :195-263

[10] Interactions between adsorbed molecules [J].

Kevan, SD .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1998, 131 (1-3) :19-30

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