Isolation and structural determination of two derivatives of the elusive carbamic acid

被引:95
作者
Aresta, M
Ballivet-Tkatchenko, D
Dell'Amico, DB
Bonnet, MC
Boschi, D
Calderazzo, F
Faure, RE
Labella, L
Marchetti, F
机构
[1] Univ Pisa, Dipartimento Chim & Chim Ind, I-56126 Pisa, Italy
[2] Univ Bari, Dipartimento Chim, I-70126 Bari, Italy
[3] Inst Rech Catalyse, CNRS, F-69626 Villeurbanne, France
[4] Univ Lyon 1, Chim Analyt Lab, F-69622 Villeurbanne, France
[5] Univ Rome La Sapienza, Dipartimento Ingn Chim Mat Mat Prime & Met, I-00185 Rome, Italy
关键词
D O I
10.1039/b002479l
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The dibenzyl-substituted carbamic acid (PhCH2)(2)NC(O)OH (1), its deprotonation product [(PhCH2)(2)NH2]- [(PhCH2)(2)NCO2] (2) and CoCl(NO)(2)[PhP(OCH2CH2)(2)NC(O)OH]. 2MeCOMe(3 . 2MeCOMe) are reported, the diffractometric study showing the carbamic acids 1 and 3 to be paired through hydrogen bonds.
引用
收藏
页码:1099 / 1100
页数:2
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