Electropolymerized nickel macrocyclic complex-based films: Design and electrocatalytic application

被引：97

作者：

Trevin, S

Bedioui, F

Villegas, MGG

BiedCharreton, C

机构：

[1] ECOLE NATL SUPER CHIM PARIS,LAB ELECTROCHIM & CHIM ANALYT,CNRS,URA 216,F-75231 PARIS 05,FRANCE

[2] ECOLE NORMALE SUPER,DEPT CHIM,LAB PHOTOPHYS & PHOTOCHIM SUPRAMOL & MACROMOL,CNRS,URA 1906,F-94235 CACHAN,FRANCE

[3] UNIV GUANAJUATO,INST INVEST CIENTIF,GUANAJUATO 36040,GTO,MEXICO

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1997年 / 7卷 / 06期

关键词：

D O I：

10.1039/a700533d

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The voltammetric behaviour of electropolymerized nickel macrocyclic complexes in alkaline aqueous solution is described. The nickel-based modified electrodes were prepared by oxidative polymerization of nickel porphyrin, nickel salen and nickel cyclam complexes by repeated potential scans in 0.1 M NaOH solution. All the electroformed films exhibited the same behaviour which is similar to that shown by nickel hydroxide-modified electrodes. In addition, the nickel complex-based polymers act as efficient materials for the electrocatalytic oxidation of methanol, ethanol and hydrazine.

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页码：923 / 928

页数：6

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