Enantioselective ring opening of meso-epoxides with tetrachlorosilane catalyzed by chiral bipyridine N,N'-dioxide derivatives

被引：107

作者：

Nakajima, M ^{[1
]}

Saito, M ^{[1
]}

Uemura, M ^{[1
]}

Hashimoto, S ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Pharmaceut Sci, Sapporo, Hokkaido 0600812, Japan

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 49期

关键词：

D O I：

10.1016/S0040-4039(02)02229-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An enantioselective ring opening of meso-epoxides with tetrachlorosilane in the presence of diisopropylethylamine exploiting chiral bipyridine N,N'-dioxides as catalysts affords the corresponding chlorohydrins in high enantioselectivities of up to 90% ee. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：8827 / 8829

页数：3

共 21 条

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