Suzuki cross-couplings on aryl (heteroaryl) bromides and chlorides with bulky aliphatic phosphines/Pd(0)-triolefinic macrocyclic catalyst

被引：26

作者：

Moreno-Manas, Marcial ^{[1
]}

Pleixats, Roser ^{[1
]}

Serra-Muns, Anna ^{[1
]}

机构：

[1] Univ Autonoma Barcelona, Dept Chem, E-08193 Barcelona, Spain

来源：

SYNLETT | 2006年 / 18期

关键词：

macrocycle; olefin complex; catalysis by palladium; recovery;

D O I：

10.1055/s-2006-948173

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The combination of a bulky aliphatic phosphine, e.g. tricyclohexylphosphine or the tetrafluoroborate salt of tri-tert-butylphosphine, with the Pd(0) complex of a 15-membered triolefinic macrocycle is an excellent catalyst for the Suzuki cross-coupling of aryl and heteroaryl bromides and chlorides. The palladium can be recovered in the form of the initial complex.

引用

页码：3001 / 3004

页数：4

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