Synthesis of densely functionalised arenes using [2+2+2] cycloaddition reactions

被引：20

作者：

Clayden, Jonathan ^{[1
]}

Moran, Wesley J. ^{[1
]}

机构：

[1] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2007年 / 5卷 / 07期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1039/b700353f

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Rh(I)-catalysed [2 + 2 + 2] cycloaddition allows the synthesis of aryl ethers and diaryl methanes containing a high degree of steric hindrance from relatively simple diyne and alkyne precursors. The diarylmethanes made in this way show no evidence in their NMR spectra, however, of rotational restriction.

引用

页码：1028 / 1030

页数：3

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