Synthesis and electrochemistry of a substituted phthalocyaninatozinc

被引：15

作者：

Ma, Chunyu

Du, Guotong ^{[1
]}

Cao, Yong

Yu, Shukun

Cheng, Chuanhui

Jiang, Wenhai

Chang, Yuchun

Wang, Xu

Cong, Fangdi

Yu, Haifeng

机构：

[1] Dalian Univ Technol, Dept Phys, State Key Lab Mat Modificat Laser Ion & Electron, Dalian 116023, Peoples R China

[2] Jilin Univ, State Key Lab Integrated Optoelect, Changchun 130012, Peoples R China

[3] NE Normal Univ, Fac Chem, Changchun 130024, Peoples R China

来源：

DYES AND PIGMENTS | 2007年 / 72卷 / 02期

基金：

中国国家自然科学基金;

关键词：

phthalocyanine; dye; synthesis; phenoxyl; electrochemistry; cyclic voltammetry;

D O I：

10.1016/j.dyepig.2005.08.024

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The synthesis of a zinc phthalocyanine (Pc) bearing four phenoxyl substituents was described and its molecular structure was fully characterized by H-1 NMR, MS, elemental analysis, UV-vis and IR, which were consistent with the proposed structure. This Pc possesses excellent solubility in polar organic solvents, such as dichloromethane and THF, and doesn't readily aggregate to the dimer. TOF-MS and elemental analysis prove its excellent purity. The compound's electrochemical redox reactions in THF occurred in the Pc ring and were quasi-reversible single-electron processes. The electrochemical reaction mechanism was proposed. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：267 / 270

页数：4

共 21 条

[1]

ALBERT K, 2001, CHEM-EUR J, V7, P2549

[2]

Brewis M, 1998, CHEM-EUR J, V4, P1633, DOI 10.1002/(SICI)1521-3765(19980904)4:9<1633::AID-CHEM1633>3.3.CO

[3]

2-F

[4] The electrochemistry of platinum phthalocyanine microcrystals III. Electrochemical behaviour in aqueous electrolytes [J].

Brown, RJC ;

Kucernak, AR .

ELECTROCHIMICA ACTA, 2001, 46 (16) :2573-2582

[5] INTRAMOLECULAR COUPLING IN METAL-FREE BINUCLEAR PHTHALOCYANINES [J].

DODSWORTH, ES ;

LEVER, ABP ;

SEYMOUR, P ;

LEZNOFF, CC .

JOURNAL OF PHYSICAL CHEMISTRY, 1985, 89 (26) :5698-5705

[6] Synthesis and spectroscopic and electrochemical studies of novel benzo- or 2,3-naphtho-fused tetraazachlorins, bacteriochlorins, and isobacteriochlorins [J].

Fukuda, T ;

Makarova, EA ;

Luk'yanets, EA ;

Kobayashi, N .

CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (01) :117-133

[7] Synthesis, characterization and HPLC-applications of novel phthalocyanine modified silica gel materials [J].

Görlach, B ;

Hellriegel, C ;

Steinbrecher, S ;

Yüksel, H ;

Albert, K ;

Plies, E ;

Hanack, M .

JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (12) :3317-3325

[8]

HANACK M, 1987, SYNTHESIS-STUTTGART, P703

[9]

HANACK M, 1993, ANGEW CHEM INT EDIT, V32, P1422, DOI 10.1002/anie.199314221

[10]

KAWO P, 1999, ORGANOMETALLICS, V18, P3528

← 1 2 3 →