The shortest C-H•••O hydrogen bonds yet determined by single crystal neutron diffraction:: a structural study of two phosphonium aryloxides

被引:26
作者
Davidson, MG [1 ]
Goeta, AE
Howard, JAB
Lamb, S
Mason, SA
机构
[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England
[2] Univ Durham, Dept Chem, Sci Labs, Durham DH1 3LE, England
[3] Inst Max Von Laue Paul Langevin, F-38042 Grenoble, France
关键词
D O I
10.1039/b001433h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The structures of two phosphonium aryloxides have been determined by neutron diffraction at 20 It and reveal extensive aggregation in the solid state via very short C-H ... O and C-H ...pi interactions, including the shortest C-H ... O distance yet determined by neutron diffraction.
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页码:477 / 479
页数:3
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