Efficient polymer-supported Sharpless alkene epoxidation catalyst

被引：54

作者：

Canali, L ^{[1
]}

Karjalainen, JK ^{[1
]}

Sherrington, DC ^{[1
]}

Hormi, O ^{[1
]}

机构：

[1] UNIV OULU,DEPT CHEM,FIN-90570 OULU,FINLAND

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 01期

关键词：

D O I：

10.1039/a606954a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Linear poly(tartrate ester) ligands provide high chemical yields and enantiomeric excesses in the epoxidation of trans-hex-2en-1-ol using Ti(OPri)(4)-tert-butyl hydroperoxide.

引用

页码：123 / 124

页数：2

共 17 条

[1]

DE BB, 1995, TETRAHEDRON-ASYMMETR, V6, P2105

[2]

FARRALL MJ, 1983, NOUV J CHIM, V7, P449

[3] MECHANISM OF ASYMMETRIC EPOXIDATION .2. CATALYST STRUCTURE [J].

FINN, MG ;

SHARPLESS, KB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (01) :113-126

[4] CATALYTIC ASYMMETRIC EPOXIDATION AND KINETIC RESOLUTION - MODIFIED PROCEDURES INCLUDING INSITU DERIVATIZATION [J].

GAO, Y ;

HANSON, RM ;

KLUNDER, JM ;

KO, SY ;

MASAMUNE, H ;

SHARPLESS, KB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (19) :5765-5780

[5]

HODGE P, 1993, MACROMOLECULES 1991, P441

[6]

HODGE P, 1994, SCI M ION EXCH RES C

[7]

HODGE P, 1990, INNOVATION PERSPECTI, P273

[8] NEW SOLID-PHASE CATALYSTS FOR ASYMMETRIC-SYNTHESIS - CROSS-LINKED POLYMERS CONTAINING A CHIRAL SHIFF BASE ZINC COMPLEX [J].

ITSUNO, S ;

SAKURAI, Y ;

ITO, K ;

MARUYAMA, T ;

NAKAHAMA, S ;

FRECHET, JMJ .

JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (01) :304-310

[9] HIGHLY ENANTIOSELECTIVE EPOXIDATION CATALYSTS DERIVED FROM 1,2-DIAMINOCYCLOHEXANE [J].

JACOBSEN, EN ;

ZHANG, W ;

MUCI, AR ;

ECKER, JR ;

DENG, L .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (18) :7063-7064

[10] THE 1ST PRACTICAL METHOD FOR ASYMMETRIC EPOXIDATION [J].

KATSUKI, T ;

SHARPLESS, KB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (18) :5974-5976

← 1 2 →