Ruthenium-catalyzed S-propargylation of thiols enables the rapid synthesis of propargylic sulfides

被引：55

作者：

Kondo, T ^{[1
]}

Kanda, Y ^{[1
]}

Baba, A ^{[1
]}

Fukuda, K ^{[1
]}

Nakamura, A ^{[1
]}

Wada, K ^{[1
]}

Morisaki, Y ^{[1
]}

Mitsudo, T ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Sakyo Ku, Kyoto 6068501, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 44期

关键词：

D O I：

10.1021/ja027750o

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new and highly efficient catalytic system based on CpRuClL2 is proposed for the S-propargylation of thiols by propargylic carbonates under neutral conditions, in which specific requirements inherent to the different reactivities of aliphatic and aromatic thiols are achieved by tuning both the nature of the ancillary ligand L and the experimental conditions. Copyright © 2002 American Chemical Society.

引用

页码：12960 / 12961

页数：2

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