Camphordisulfonamides:: good chiral ligands for the addition of dialkylzinc to aliphatic aldehydes

被引：56

作者：

Prieto, O ^{[1
]}

Ramón, DJ ^{[1
]}

Yus, M ^{[1
]}

机构：

[1] Univ Alicante, Fac Ciencias, Dept Quim Organ, E-03080 Alicante, Spain

来源：

TETRAHEDRON-ASYMMETRY | 2000年 / 11卷 / 07期

关键词：

D O I：

10.1016/S0957-4166(00)00100-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation of several disulfonamides derived from camphor and their use in the titanium tetra-isopropoxide-promoted enantioselective addition of dialkylzinc to aldehydes is described. The enantiomeric ratio is up to 98:2, the best results being obtained for aliphatic aldehydes. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：1629 / 1644

页数：16

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