Bifunctional Green Iridium Dendrimers with a "Self-Host" Feature for Highly Efficient Nondoped Electrophosphorescent Devices

被引:134
作者
Ding, Junqiao [1 ]
Wang, Bin [2 ,3 ]
Yue, Zhengyu [2 ,3 ]
Yao, Bing [1 ]
Xie, Zhiyuan [1 ]
Cheng, Yanxiang [1 ]
Wang, Lixiang [1 ]
Jing, Xiabin [1 ]
Wang, Fosong [1 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
[2] Heilongjiang Univ, Minist Educ, Sch Chem & Mat Sci, Harbin 150080, Peoples R China
[3] Heilongjiang Univ, Minist Educ, Key Lab Fundamental Inorgan Mat Chem, Harbin 150080, Peoples R China
基金
中国国家自然科学基金;
关键词
carbazoles; dendrimers; electrophosphorescent devices; iridium; luminescence; LIGHT-EMITTING-DIODES; CARBAZOLE COMPOUNDS; TRIPLET EMITTERS; PHOSPHORESCENCE; COMPLEXES; DENDRONS; ENERGY;
D O I
10.1002/anie.200902954
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Better without doping: Use of a dendron with a high carbazole density around an iridium core has been found to improve the performance of nondoped electrophosphorescent devices more effectively than the use of higher-generation dendrimers. A promising efficiency as high as 45.7 cd A-1 (13.4 %) together with a high luminance is obtained for 6 B-G1 (see picture). These values are very close to those of the corresponding doped device. © 2009 Wiley-VCH Verlag GmbH & Co. KCaA.
引用
收藏
页码:6664 / 6666
页数:3
相关论文
共 22 条
[1]  
[Anonymous], 2001, ANGEW CHEM
[2]   Very high-efficiency green organic light-emitting devices based on electrophosphorescence [J].
Baldo, MA ;
Lamansky, S ;
Burrows, PE ;
Thompson, ME ;
Forrest, SR .
APPLIED PHYSICS LETTERS, 1999, 75 (01) :4-6
[3]   Highly efficient phosphorescent emission from organic electroluminescent devices [J].
Baldo, MA ;
O'Brien, DF ;
You, Y ;
Shoustikov, A ;
Sibley, S ;
Thompson, ME ;
Forrest, SR .
NATURE, 1998, 395 (6698) :151-154
[4]   Carbazole compounds as host materials for triplet emitters in organic light-emitting diodes:: Tuning the HOMO level without influencing the triplet energy in small molecules [J].
Brunner, K ;
van Dijken, A ;
Börner, H ;
Bastiaansen, JJAM ;
Kiggen, NMM ;
Langeveld, BMW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (19) :6035-6042
[5]   Highly efficient green-emitting phosphorescent iridium dendrimers based on carbazole dendrons [J].
Ding, JQ ;
Gao, J ;
Cheng, YX ;
Xie, ZY ;
Wang, LX ;
Ma, DG ;
Jing, XB ;
Wang, FS .
ADVANCED FUNCTIONAL MATERIALS, 2006, 16 (04) :575-581
[6]   Solution-Processible Red Iridium Dendrimers based on Oligocarbazole Host Dendrons: Synthesis, Properties, and their Applications in Organic Light-Emitting Diodes [J].
Ding, Junqiao ;
Lu, Jianhong ;
Cheng, Yanxiang ;
Xie, Zhiyuan ;
Wang, Lixiang ;
Jing, Xiabin ;
Wang, Fosong .
ADVANCED FUNCTIONAL MATERIALS, 2008, 18 (18) :2754-2762
[7]   Control of Charge Transport in Iridium(III) Complex-Cored Carbazole Dendrimers by Generation and Structural Modification [J].
Gambino, Salvatore ;
Stevenson, Stuart G. ;
Knights, Kevin A. ;
Burn, Paul L. ;
Samuel, Ifor D. W. .
ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (02) :317-323
[8]  
Hecht S, 2001, ANGEW CHEM INT EDIT, V40, P74, DOI 10.1002/1521-3773(20010105)40:1<74::AID-ANIE74>3.0.CO
[9]  
2-C
[10]   Blue organic electrophosphorescence using exothermic host-guest energy transfer [J].
Holmes, RJ ;
Forrest, SR ;
Tung, YJ ;
Kwong, RC ;
Brown, JJ ;
Garon, S ;
Thompson, ME .
APPLIED PHYSICS LETTERS, 2003, 82 (15) :2422-2424