Structures and oxide mobility in Bi-Ln-O materials:: Heritage of Bi2O3

被引：246

作者：

Drache, Michel ^{[1
]}

Roussel, Pascal ^{[1
]}

Wignacourt, Jean-Pierre ^{[1
]}

机构：

[1] CNRS, UMR 8181, Unite Catalyse & Chim Solide, F-59652 Villeneuve Dascq, France

来源：

CHEMICAL REVIEWS | 2007年 / 107卷 / 01期

关键词：

D O I：

10.1021/cr050977s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A review is given of the lanthanide bismuth based oxides family which exhibits a wide diversity of phases with a common Bi2O3-related structure that is either stable or metastable at moderate or low temperature. Topics discussed include Bi2O3 polymorphishm, Bi1-xLnxO1.5 stable α- and δ-phases, Bi1-xLnxO1.5 β and δ metastable phases, Bi1-xLnxO1.5 rhombohedral Bi-Sr-O type phases (Ln = La-Er, Y), orthorhombic Bi17Ln7O36 type phases (Ln = Tm-Lu), ordered cubic Bi5Ln3O12 type phases (Ln = Sm-Yb), triclinic BiLnO3 type phases (Ln = Dy-Lu, Y) and Bi1-xLnxO1.5 phases (x ≥ 0.5; Ln = La-Ho, Y).

引用

页码：80 / 96

页数：17

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