Characteristics of nanosized ruthenium metal by chemical reduction method.

被引：10

作者：

Lee, DS ^{[1
]}

Liu, TK ^{[1
]}

机构：

[1] Natl Taiwan Univ, Dept Geosci, Taipei 106, Taiwan

来源：

JOURNAL OF NON-CRYSTALLINE SOLIDS | 2002年 / 311卷 / 03期

关键词：

D O I：

10.1016/S0022-3093(02)01627-7

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Nano-sized Ru metals have been prepared by the chemical reduction of ruthenium chloride and ruthenium hydroxide. Sodium borohydride was used as a reducing agent. The samples have been characterized by elemental analysis, X-ray diffraction, differential scanning calorimetry, and transmission electron microscopy. The preparation method greatly affects the composition and surface area of the material. All the samples show nanosized particles. However, samples prepared by reduction of ruthenium hydroxide had a lower surface area and larger particle size than those prepared by reduction of ruthenium chloride. Residual amount of boron was present in the samples. The samples demonstrate amorphous structure. (C) 2002 Elsevier Science B.V. All rights reserved.

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页码：323 / 327

页数：5

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