Synthesis, crystal structure and solution behavior of a novel tetranuclear Zn(II) Schiff base complex

被引：25

作者：

Hermann, J ^{[1
]}

Erxleben, A ^{[1
]}

机构：

[1] Univ Dortmund, Fachbereich Chem, D-44221 Dortmund, Germany

来源：

INORGANICA CHIMICA ACTA | 2000年 / 304卷 / 01期

关键词：

Schiff base complexes; zinc complexes; crystal structures;

D O I：

10.1016/S0020-1693(00)00064-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The tetranuclear Zn(II) Schiff base complex [Mg(H2O)(6)][{Zn2L1(CH3CO2)}(2)(mu(3)-OH)(2)]. 6H(2)O (H3L1 = Schiff base derived from 2,6-diformyl-4-methyIphenol and glycine) (2) has been prepared and structurally characterized. The complex anion consists of two identical dinuclear Zn-2/L-1 subunits connected through mu(3)-OH bridges. While 2, with Mg(H2O)(6)(2+) serving as counterion, crystallized from aqueous solution, solution studies in DMSO indicated substitution of zinc by magnesium and formation of the heteronuclear complex [ZnMgL1](+). (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：125 / 129

页数：5

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