N-N2 state to state vibrational-relaxation and dissociation rates based on quasiclassical calculations

被引：163

作者：

Esposito, F.

Armenise, I.

Capitelli, M.

机构：

[1] CNR, IMIP, I-70126 Bari, Italy

[2] Univ Bari, Dept Chem, I-70126 Bari, Italy

来源：

CHEMICAL PHYSICS | 2006年 / 331卷 / 01期

关键词：

vibrational energy exchange; rate coefficients; dissociation; atom-molecule collisions; nitrogen;

D O I：

10.1016/j.chemphys.2006.09.035

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Interpolation formulas are presented to reproduce the rate coefficients for vibrational-translational energy exchange and dissociation for the N + N-2 collision process. The original data have been obtained by quasiclassical method in a detailed way, including the effect of molecular rotation. The fitting procedure results are compared with original data and the related error is evaluated. Comparison with global experimental dissociation results is also presented. (c) 2006 Elsevier B.V. All rights reserved.

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页码：1 / 8

页数：8

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