Electronically excited states in size selected solvated alkali metal atoms .2. Isotope effects in the spectroscopy of sodium water and sodium ammonia complexes

被引：39

作者：

Schulz, CP ^{[1
]}

Nitsch, C ^{[1
]}

机构：

[1] UNIV FREIBURG,FAK PHYS,D-7800 FREIBURG,GERMANY

来源：

JOURNAL OF CHEMICAL PHYSICS | 1997年 / 107卷 / 23期

关键词：

D O I：

10.1063/1.475277

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The change of spectroscopic properties of sodium-watek and sodium-ammonia complexes upon deuteration is investigated. The ionization potential of NaD2O is shifted by 70 cm(-1) towards lower energies compared to NaH2O. A shift of 81 cm(-1) between NaND3 and NaNH3 is observed again towards lower energies. From these shift the vibrational frequencies for the ground state of the neutral and ionic complex have been estimated. The first electronically excited state ((A) over tilde(2)E) of NaND3 has been investigated by resonant two color two photon ionization. The comparison with the formerly observed NaNH3 spectrum enables us to do an unequivocal assignment of the vibrational structure. (C) 1997 American Institute of Physics. [S0021-9606(97)01646-2].

引用

页码：9794 / 9800

页数：7

共 17 条

[1] HYDRATION OF SODIUM IN WATER CLUSTERS [J].