STM spectroscopy of magnetic molecules

被引：47

作者：

Petukhov, K. ^{[1
]}

Alam, M. S. ^{[1
]}

Rupp, H. ^{[1
]}

Stroemsdoerfer, S. ^{[1
]}

Mueller, P. ^{[1
]}

Scheurer, A. ^{[2
]}

Saalfrank, R. W. ^{[2
]}

Kortus, J. ^{[3
]}

Postnikov, A. ^{[4
]}

Ruben, M. ^{[5
]}

Thompson, L. K. ^{[6
]}

Lehn, J-M. ^{[7
]}

机构：

[1] Univ Erlangen Nurnberg, Dept Phys, D-91058 Erlangen, Germany

[2] Univ Erlangen Nurnberg, Dept Chem & Pharm, D-8520 Erlangen, Germany

[3] TU Bergakad Freiberg, Inst Theoret Phys, Freiberg, Germany

[4] Univ Paul Verlaine, Lab Phys Milieux Denses, Metz, France

[5] Forschungszentrum Karlsruhe, Inst Nanotechnol, D-76021 Karlsruhe, Germany

[6] Mem Univ Newfoundland, Dept Chem, St John, NF A1B 3X7, Canada

[7] Univ Strasbourg, ISIS, Strasbourg, France

来源：

COORDINATION CHEMISTRY REVIEWS | 2009年 / 253卷 / 19-20期

关键词：

Scanning tunneling microscopy; Current-imaging tunneling spectroscopy; Scanning tunneling spectroscopy; Single-molecule magnets; Grid-like and star-like supramolecular assemblies; CO-II COMPLEXES; METAL CENTERS; ZN-II; LIGAND; ARCHITECTURES; BEHAVIOR; ARRAYS; GRAPHITE; DEVICES;

D O I：

10.1016/j.ccr.2009.01.024

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We have investigated a series of magnetic supramolecular complexes involving coordinated metal ions. Using the current-imaging tunneling spectroscopy mode of a STM, we mapped isolated single molecules. By comparing with DFT calculations, we confirmed that the weakest bonds, i.e. the supramolecular coordination interactions, dominate the molecular orbitals near the Fermi-level of the molecule. Thus, STM spectroscopy can address directly the metal centers in a rather complex molecular entity. Our method allows a selective mapping of the functional units within the supramolecular architecture, even if these units are embedded into a complex set of organic ligands. We observed this behavior in all of our investigated molecules. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：2387 / 2398

页数：12

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