General entries to C-aryl glycosides.: Formal synthesis of galtamycinone

被引：46

作者：

Apsel, B ^{[1
]}

Bender, JA ^{[1
]}

Escobar, M ^{[1
]}

Kaelin, DE ^{[1
]}

Lopez, OD ^{[1
]}

Martin, SF ^{[1
]}

机构：

[1] Univ Texas, Dept Chem & Biochem, Austin, TX 78712 USA

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 05期

基金：

美国国家卫生研究院;

关键词：

C-aryl glycosides; Diels-Alder reaction; palladium-catalyzed ring openings;

D O I：

10.1016/S0040-4039(02)02666-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Utilizing a general entry we had developed for the synthesis of C-aryl glycosides, we have prepared the juglone derivatives 18-20 as well as the juglone precursor 13. Because 19 had been previously converted in two steps by Suzuki into galtamycinone (1), its preparation constitutes a total synthesis of 1. (C) 2003 Elsevier Science Ltd. All rights reserved.

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收藏

页码：1075 / 1077

页数：3

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