Regio- and stereoselective reductive opening of diene-ester derived monoepoxides with palladium catalyst and dimethylamine-borane complex

被引：25

作者：

David, H ^{[1
]}

Dupuis, L ^{[1
]}

Guillerez, MG ^{[1
]}

Guibé, F ^{[1
]}

机构：

[1] Univ Paris 11, Associe CNRS, Lab Catalyse Mol, Inst Chim Mol Orsay, F-91405 Orsay, France

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 18期

关键词：

palladium catalysis; amine-borane complexes; epoxide hydrogenolysis;

D O I：

10.1016/S0040-4039(00)00380-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Monoepoxides of diene-esters are regio- and stereoselectively reduced to homoallylic alcohols by dimethylamine-borane complex in the presence of acetic acid and catalytic amounts of Pd(PPh3)(4). (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：3335 / 3338

页数：4

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