Determination of kinetic parameters for complex heterogeneous catalytic reactions by numerical evaluation of TAP experiments

被引：40

作者：

Soick, M ^{[1
]}

Wolf, D ^{[1
]}

Baerns, M ^{[1
]}

机构：

[1] Ruhr Univ Bochum, Lehrstuhl Tech Chem, D-44780 Bochum, Germany

来源：

CHEMICAL ENGINEERING SCIENCE | 2000年 / 55卷 / 15期

关键词：

temporal analysis; methane oxidation; synthesis gas; kinetics;

D O I：

10.1016/S0009-2509(99)00553-9

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

A numerical method is introduced for deriving kinetic parameters by evaluating responses to transient concentration inputs to a catalytic fixed-bed reactor under vacuum conditions (TAP). Complex reaction networks without restrictions regarding the number of reaction steps and the reaction orders are investigated. The method was successfully applied for the estimation of rate constants of parallel and consecutive surface reactions in the oxidative conversion of methane to syngas over a magnesia-supported Pt catalyst. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：2875 / 2882

页数：8

共 23 条

[1]

[Anonymous], NUMERICAL RECIPES FO

[2]

Baerns M, 1997, STUD SURF SCI CATAL, V107, P421

[3] TRANSIENT KINETICS FROM THE TAP REACTOR SYSTEM - APPLICATION TO THE OXIDATION OF PROPYLENE TO ACROLEIN [J].

CRETEN, G ;

LAFYATIS, DS ;

FROMENT, GF .

JOURNAL OF CATALYSIS, 1995, 154 (01) :151-162

[4] THE CHARACTERIZATION OF CARBONACEOUS SPECIES ON RUTHENIUM CATALYSTS WITH C-13 NUCLEAR MAGNETIC-RESONANCE SPECTROSCOPY [J].

DUNCAN, TM ;

WINSLOW, P ;

BELL, AT .

JOURNAL OF CATALYSIS, 1985, 93 (01) :1-22

[5] CATALYTIC AIR PURIFICATION - CHALLENGES AND NEW SOLUTIONS [J].

EIGENBERGER, G ;

NIEKEN, U .

CHEMIE INGENIEUR TECHNIK, 1991, 63 (08) :781-791

[6] TEMPORAL ANALYSIS OF PRODUCTS (TAP) - A UNIQUE CATALYST EVALUATION SYSTEM WITH SUBMILLISECOND TIME RESOLUTION [J].

GLEAVES, JT ;

EBNER, JR ;

KUECHLER, TC .

CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 1988, 30 (01) :49-116

[7] TAP-2: An interrogative kinetics approach [J].

Gleaves, JT ;

Yablonskii, GS ;

Phanawadee, P ;

Schuurman, Y .

APPLIED CATALYSIS A-GENERAL, 1997, 160 (01) :55-88

[8] Selective synthesis of maleic anhydride by spatial separation of n-butane oxidation and catalyst reoxidation [J].

Golbig, KG ;

Werther, J .

CHEMICAL ENGINEERING SCIENCE, 1997, 52 (04) :583-595

[9]

HOHENBERGER M, 1997, THESIS RUHR U BOCHUM

[10] Methane reforming reaction with carbon dioxide over Ni/SiO2 catalyst .1. Deactivation studies [J].

Kroll, VCH ;

Swaan, HM ;

Mirodatos, C .

JOURNAL OF CATALYSIS, 1996, 161 (01) :409-422

← 1 2 3 →