Reversible H2 splitting between Ru(II) and a remote carbanion in a zwitterionic compound

被引：30

作者：

Stepowska, Elzbieta ^{[1
]}

Jiang, Huiling ^{[1
]}

Song, Datong ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, Davenport Chem Res Labs, Toronto, ON M5S 1A1, Canada

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 04期

基金：

加拿大自然科学与工程研究理事会;

关键词：

FRUSTRATED LEWIS PAIRS; RUTHENIUM COMPLEXES; CATALYTIC-HYDROGENATION; ACTIVATION; DIHYDROGEN; FACILE; CLEAVAGE; BONDS; REACTIVITY; RHODIUM(I);

D O I：

10.1039/b919606d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report a reversible long-range splitting of H-2 between a Ru(II) center and a remote carbanion in a zwitterionic compound.

引用

页码：556 / 558

页数：3

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