Real-time single-molecule imaging of the formation and dynamics of coordination compounds

被引:191
作者
Lin, N
Dmitriev, A
Weckesser, J
Barth, JV
Kern, K
机构
[1] Max Planck Inst Festkorperforsch, D-70569 Stuttgart, Germany
[2] Ecole Polytech Fed Lausanne, Inst Phys Nanostruct, CH-1015 Lausanne, Switzerland
关键词
D O I
10.1002/anie.200290046
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Reaction sequences under the microscope: Scanning tunneling microscopy has been used to follow the association and dissociation of the cloverleaf-shaped complex from 1,3,5-benzenetricarboxylic acid and Cu atoms from a metal surface one molecule at a time (see images). The lifetime of the complexes depends crucially on their local chemical enviroment.
引用
收藏
页码:4779 / 4783
页数:5
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