Improvement in corrosion properties of carbon-coated Fe-based metals for PEFC bipolar plate

被引:11
作者
Fukutsuka, Tornokazu
Yamaguchi, Takayuki
Matsuo, Yoshiaki
Sugie, Yosohiro
Ogumi, Zernpachi
机构
[1] Univ Hyogo, Grad Sch Engn, Himeji, Hyogo 6712201, Japan
[2] Kyoto Univ, Grad Sch Engn, Nishikyo Ku, Kyoto 6158510, Japan
关键词
PEFC; bipolar plate; carbonaceous thin film; corrosion;
D O I
10.5796/electrochemistry.75.152
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Low cost metals are quite attractive as bipolar plate of polymer electrolyte fuel cell (PEFC). However, low cost metals easily corrode due to the absence of good passivation films. In order to give high electrical conductivity and corrosion resistance to low cost metals such as carbon steel (S25C), carbon-coat was carried out by plasma-assisted chemical vapor deposition. Carbon-coated samples were characterized by XRD, Raman spectroscopy, and interfacial contact resistance. Based on the results of polarization measurement, the combination of carbon-coat and electroless nickel plating was found to be effective for decreasing of anodic dissolution of base metal.
引用
收藏
页码:152 / 154
页数:3
相关论文
共 14 条
[1]  
Abe T, 1999, CARBON, V37, P1165
[2]  
Arita M, 2002, FUEL CELLS, V2, P10, DOI 10.1002/1615-6854(20020815)2:1<10::AID-FUCE10>3.0.CO
[3]  
2-#
[4]  
Borup RL, 1995, MATER RES SOC SYMP P, V393, P151, DOI 10.1557/PROC-393-151
[5]   Electrochemical properties of carbonaceous thin films prepared by plasma chemical vapor deposition [J].
Fukutsuka, T ;
Abe, T ;
Inaba, M ;
Ogumi, Z .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (11) :A1260-A1265
[6]   Study on the crystallization process of Ni-P amorphous alloy [J].
Li, HX ;
Chen, HY ;
Dong, SH ;
Yang, JS ;
Deng, JF .
APPLIED SURFACE SCIENCE, 1998, 125 (01) :115-119
[7]   Review of bipolar plates in PEM fuel cells: Flow-field designs [J].
Li, XG ;
Sabir, M .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2005, 30 (04) :359-371
[8]   Synthesis of Invar alloy powders by electroless plating [J].
Lin, KY ;
Yang, TJ ;
Tsai, WT .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2006, 416 (1-2) :226-231
[9]   Review and analysis of PEM fuel cell design and manufacturing [J].
Mehta, V ;
Cooper, JS .
JOURNAL OF POWER SOURCES, 2003, 114 (01) :32-53
[10]   RAMAN SPECTRUM OF GRAPHITE [J].
TUINSTRA, F ;
KOENIG, JL .
JOURNAL OF CHEMICAL PHYSICS, 1970, 53 (03) :1126-&