Pressure-composition isotherms of the Mg2Ni0.75Fe0.25-Mg system synthesized by replacement-diffusion method

被引:35
作者
Yuan, HT [1 ]
Yang, HB [1 ]
Zhou, ZX [1 ]
Song, DY [1 ]
Zhang, YS [1 ]
机构
[1] NANKAI UNIV,INST NEW ENERGY MAT CHEM,TIANJIN 300071,PEOPLES R CHINA
基金
美国国家科学基金会;
关键词
hydrogen desorption; replacement-diffusion method; hydrogen-storage system; magnesium; nickel and iron;
D O I
10.1016/S0925-8388(97)00170-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The hydrogen-storage system Mg2Ni0.75Fe0.25-Mg (molar ratio is 2:1) has been successfully synthesized by the replacement-diffusion method (RDM). A study of the hydrogen desorption process was carried out. The results indicated that the pressure-composition isotherm (P-C-T) characteristics, plateau pressure and storage capacity change with temperature. The present system corresponds to a new hydrogen storage material with an optimum storage-capacity (3.3 wt.%). (C) 1997 Elsevier Science S.A.
引用
收藏
页码:256 / 259
页数:4
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