Pyridine conversion in a flow reactor and its interaction with nitric oxide

被引：23

作者：

Alzueta, MU ^{[1
]}

Tena, A ^{[1
]}

Bilbao, R ^{[1
]}

机构：

[1] Univ Zaragoza, Ctr Politecn Super, Dept Environm Chem & Engn, Zaragoza, Spain

来源：

COMBUSTION SCIENCE AND TECHNOLOGY | 2002年 / 174卷 / 10期

关键词：

pyridine; volatile nitrogen; kinetic modeling;

D O I：

10.1080/00102200290021470

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

An experimental study of the oxidation of pyridine both in the absence and in the presence of NO has been performed. The experiments were conducted in an isothermal quartz flow reactor at atmospheric pressure in the temperature range 700-1500 K. The influence of temperature, air excess ratio (corresponding to fuel-rich, stoichiometric, and lean conditions), and NO on the concentrations Of CO, CO2, HCN, and NO has been analyzed. The current work contributes to a series of works on the conversion of volatile nitrogen compounds with experimental results related to pyridine. Also, a reaction mechanism based on various literature mechanisms has been used for simulating the experimental results.

引用

页码：151 / 169

页数：19

共 28 条

[1]

Alzueta MU, 2000, INT J CHEM KINET, V32, P498, DOI 10.1002/1097-4601(2000)32:8<498::AID-KIN8>3.0.CO

[2]

2-H

[3]

Alzueta MU, 1998, INT J CHEM KINET, V30, P683, DOI 10.1002/(SICI)1097-4601(1998)30:9<683::AID-KIN9>3.0.CO

[4]

2-O

[5]

Alzueta MU, 1999, ISRAEL J CHEM, V39, P73

[6]

ALZUETA MU, 2000, P COMBUST INST, V28, P113

[7] REACTIONS OF FUEL-NITROGEN COMPOUNDS UNDER CONDITIONS OF INERT PYROLYSIS [J].

AXWORTHY, AE ;

DAYAN, VH ;

MARTIN, GB .

FUEL, 1978, 57 (01) :29-35

[8] SIMPLIFIED KINETIC-MODEL OF THE CHEMISTRY IN THE REBURNING ZONE USING NATURAL-GAS [J].

BILBAO, R ;

ALZUETA, MU ;

MILLERA, A ;

DUARTE, M .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1995, 34 (12) :4540-4548

[9]

BURCAT A, 1995, 732 TAE TECHN ISR I

[10]

FRIEDRICHS H, 1990, Z PHYS CHEM, V166, P157

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