Copper(II)bis((trifluoromethyl)sulfonyl)amide. A novel Lewis acid catalyst in Diels-Alder reactions of cyclopentadiene with methyl vinyl ketone

被引：30

作者：

Nie, J

Kobayashi, H

Sonoda, T

机构：

[1] KYUSHU UNIV,INST ADV MAT STUDY,KASUGA,FUKUOKA 816,JAPAN

[2] HUAZHONG UNIV SCI & TECHNOL,WUHAN 430074,WUBEI,PEOPLES R CHINA

来源：

CATALYSIS TODAY | 1997年 / 36卷 / 01期

关键词：

Diels-Alder reaction; Lewis acid; catalytic effect; metal salts;

D O I：

10.1016/S0920-5861(96)00199-X

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Copper(II) salt of weakly coordinating bis((trifluoromethyl)sulfonyl)amide anion was newly prepared. A remarkable catalytic effect of the copper salt Cu(NTf2)(2) was demonstrated in the Diels-Alder reactions of cyclopentadiene with methyl vinyl ketone in CH2Cl2 in comparison with other metal salts.

引用

页码：81 / 84

页数：4

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