Rotational relaxation in ultracold CO plus He collisions

被引:21
作者
Florian, PM [1 ]
Hoster, M [1 ]
Forrey, RC [1 ]
机构
[1] Penn State Univ, Berks Lehigh Valley Coll, Reading, PA 19610 USA
来源
PHYSICAL REVIEW A | 2004年 / 70卷 / 03期
基金
美国国家科学基金会;
关键词
D O I
10.1103/PhysRevA.70.032709
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Cold and ultracold collisions involving rotationally hot CO molecules are investigated using quantum mechanical coupled channel, coupled states, and effective potential scattering formulations. Quenching rate coefficients are given for initial rotational levels near the dissociation threshold. The stability of the CO "super rotors" against collisional decay is compared to previous investigations involving homonuclear molecules. It is found that quasiresonant transitions provide a significantly stronger contribution to the total relaxation rate than in the comparable case of O-2. As in the case of H-2, sharp structures in the distribution of total quenching rate coefficients are found at rotational levels where quasiresonant scattering is not allowed.
引用
收藏
页码:032709 / 1
页数:7
相关论文
共 40 条
[1]   THE THEORY OF SCATTERING BY A RIGID ROTATOR [J].
ARTHURS, AM ;
DALGARNO, A .
PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1960, 256 (1287) :540-551
[2]   Vibrational relaxation of CO by collisions with 4He at ultracold temperatures [J].
Balakrishnan, N ;
Dalgarno, A ;
Forrey, RC .
JOURNAL OF CHEMICAL PHYSICS, 2000, 113 (02) :621-627
[3]   Trapping neutral molecules in a traveling potential well [J].
Bethlem, HL ;
Berden, G ;
van Roij, AJA ;
Crompvoets, FMH ;
Meijer, G .
PHYSICAL REVIEW LETTERS, 2000, 84 (25) :5744-5747
[4]   Electrostatic trapping of ammonia molecules [J].
Bethlem, HL ;
Berden, G ;
Crompvoets, FMH ;
Jongma, RT ;
van Roij, AJA ;
Meijer, G .
NATURE, 2000, 406 (6795) :491-494
[5]   Decelerating neutral dipolar molecules [J].
Bethlem, HL ;
Berden, G ;
Meijer, G .
PHYSICAL REVIEW LETTERS, 1999, 83 (08) :1558-1561
[6]   Quenching of vibrationally excited CO(ν=2) molecules by ultra-cold collisions with 4He atoms [J].
Bodo, E ;
Gianturco, FA ;
Dalgarno, A .
CHEMICAL PHYSICS LETTERS, 2002, 353 (1-2) :127-130
[7]   BUFFER-GAS LOADING OF ATOMS AND MOLECULES INTO A MAGNETIC TRAP [J].
DOYLE, JM ;
FRIEDRICH, B ;
KIM, J ;
PATTERSON, D .
PHYSICAL REVIEW A, 1995, 52 (04) :R2515-R2518
[8]   Buffer-gas cooling of atomic and molecular beams -: art. no. 043401 [J].
Egorov, D ;
Lahaye, T ;
Schöllkopf, W ;
Friedrich, B ;
Doyle, JM .
PHYSICAL REVIEW A, 2002, 66 (04) :8
[9]   Cold collisions between argon atoms and hydrogen molecules [J].
Flasher, JC ;
Forrey, RC .
PHYSICAL REVIEW A, 2002, 65 (03) :8
[10]   Emission spectrum for polar super rotors in a cold buffer gas [J].
Forrey, RC .
EUROPEAN PHYSICAL JOURNAL D, 2004, 31 (02) :409-415