The first organoruthenium(IV) complexes containing nitrogen donor ligands by oxidative addition of allylic substrates to coordinatively unsaturated Ru(II) complexes

被引:50
作者
Kondo, H
Yamaguchi, Y
Nagashima, H [1 ]
机构
[1] Kyushu Univ, Inst Adv Mat Study, Fukuoka 8168580, Japan
[2] JST, CREST, Wako, Saitama, Japan
关键词
D O I
10.1039/b002927k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Oxidative addition of allylic substrates to coordinatively unsaturated ruthenium(ii), (eta(5)-C5Me5)Ru(amidinate) complexes, afford cationic ruthenium(iv) compounds, [(eta(5)-C5Me5)Ru(amidinate)(eta(3)-allyl)](+), which have been characterized by spectroscopic analysis and X-ray structure determination.
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收藏
页码:1075 / 1076
页数:2
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