Nanostructured Calcite Single Crystals with Gyroid Morphologies

被引：96

作者：

Finnemore, Alexander S. ^{[1
]}

Scherer, Maik R. J. ^{[1
]}

Langford, Richard ^{[1
]}

Mahajan, Sumeet ^{[1
]}

Ludwigs, Sabine ^{[2
]}

Meldrum, Fiona C. ^{[3
]}

Steiner, Ullrich ^{[1
,2
]}

机构：

[1] Univ Cambridge, Dept Phys, Cambridge CB3 0HE, England

[2] Univ Freiburg, FRIAS, D-79104 Freiburg, Germany

[3] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England

来源：

ADVANCED MATERIALS | 2009年 / 21卷 / 38-39期

基金：

英国工程与自然科学研究理事会;

关键词：

SELF-ASSEMBLED MONOLAYERS; BLOCK-COPOLYMER; CARBONATE; PHASE; FABRICATION; CRYSTALLIZATION; PRECIPITATION; POLYSTYRENE; TEMPLATES; PROTEINS;

D O I：

10.1002/adma.200900615

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Gyroid-structured calcite crystals are grown by templating though self-assembled copolymer films. The remarkable triply periodic minimal surface is perfectly replicated on the nanometer scale, while single crystallinity is maintained. This is a wholly synthetic route to a crystal morphology found in biological systems, only on a smaller length scale.

引用

页码：3928 / +

页数：6

共 40 条

[1] A CHEMICAL-MODEL FOR THE COOPERATION OF SULFATES AND CARBOXYLATES IN CALCITE CRYSTAL NUCLEATION - RELEVANCE TO BIOMINERALIZATION
ADDADI, L
MORADIAN, J
SHAY, E
MAROUDAS, NG
WEINER, S
[J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1987, 84 (09) : 2732 - 2736
[2] Oriented growth of calcite controlled by self-assembled monolayers of functionalized alkanethiols supported on gold and silver
Aizenberg, J
Black, AJ
Whitesides, GH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (18) : 4500 - 4509
[3] Direct fabrication of large micropatterned single crystals
Aizenberg, J
Muller, DA
Grazul, JL
Hamann, DR
[J]. SCIENCE, 2003, 299 (5610) : 1205 - 1208
[4] Mimicking the function of eggshell matrix proteins: The role of multiplets of charged amino acid residues and self-assembly of peptides in biomineralization
Ajikumar, PK
Vivekanandan, S
Lakshminarayanan, R
Jois, SDS
Kini, RM
Valiyaveettil, S
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (34) : 5476 - 5479
[5] X-RAY DIFFRACTION STUDIES OF ECHINODERM PLATES
DONNAY, G
PAWSON, DL
[J]. SCIENCE, 1969, 166 (3909) : 1147 - &
[6] Control of aragonite or calcite polymorphism by mollusk shell macromolecules
Falini, G
Albeck, S
Weiner, S
Addadi, L
[J]. SCIENCE, 1996, 271 (5245) : 67 - 69
[7] Acceleration of calcite kinetics by abalone nacre proteins
Fu, G
Qiu, SR
Orme, CA
Morse, DE
De Yoreo, JJ
[J]. ADVANCED MATERIALS, 2005, 17 (22) : 2678 - +
[8] THE GYROID - A NEW EQUILIBRIUM MORPHOLOGY IN WEAKLY SEGREGATED DIBLOCK COPOLYMERS
HAJDUK, DA
HARPER, PE
GRUNER, SM
HONEKER, CC
KIM, G
THOMAS, EL
FETTERS, LJ
[J]. MACROMOLECULES, 1994, 27 (15) : 4063 - 4075
[9] Hamley I. W., 1998, The Physics of Block Copolymers
[10] Identification of the "voided double-gyroid-channel": A new morphology in block copolymers
Hashimoto, Takeji
Nishikawa, Yukihiro
Tsutsumi, Kiyoharu
[J]. MACROMOLECULES, 2007, 40 (04) : 1066 - 1072

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