Solvothermal synthesis, nanocrystal print and photoelectrochemical properties of CuInS2 thin film

被引:34
作者
Long, Fei [1 ,2 ]
Wang, Wei-Min [1 ]
Tao, Hua-chao [2 ]
Jia, Tie-Kun [1 ]
Li, Xiao-Min [2 ]
Zou, Zheng-guang [2 ]
Fu, Zheng-yi [1 ]
机构
[1] Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Peoples R China
[2] Guilin Univ Technol, Minist Educ, Key Lab New Proc Technol Nonferrous Met & Mat, Guilin 541004, Peoples R China
基金
中国国家自然科学基金;
关键词
CuInS2; Nanomaterials; Solar energy materials; Solvothermal synthesis; SOLAR-CELLS; ROUTE; INKS;
D O I
10.1016/j.matlet.2009.10.044
中图分类号
T [工业技术];
学科分类号
120111 [工业工程];
摘要
CuInS2 nanoflakes were synthesized successfully by a convenient solvothermal route in ethylene glycol under the open-air condition using copper chloride, indium chloride and thiourea as starting materials. The factors which might affect the purity of the product during the synthesis were discussed. It's found that the products were significantly affected by the reaction time, temperature and the diffusion of the reactors. CuInS2 nanoflakes ink was prepared and coated onto Mo substrate using blade technology, and after sintering, a dense and Compact CuInS2 film was produced. The morphological of the precursor films and CuInS2 films were done by scanning electron microscope (SEM), and the photoelectrochernical properties and morphology of the CuInS2 thin film were characterized. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:195 / 198
页数:4
相关论文
共 10 条
[1]
Shape-controlled synthesis of ternary chalcogenide ZnIn2S4 and CuIn(S,Se)2 nano-/microstructures via facile solution route [J].
Gou, Xinglong ;
Cheng, Fangyi ;
Shi, Yunhui ;
Zhang, Li ;
Peng, Shengjie ;
Chen, Jun ;
Shen, Panwen .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (22) :7222-7229
[2]
Guillemoles JF, 1999, ADV MATER, V11, P957, DOI 10.1002/(SICI)1521-4095(199908)11:11<957::AID-ADMA957>3.0.CO
[3]
2-1
[4]
Development of CuInSe2 nanocrystal and nanoring inks for low-cost solar cells [J].
Guo, Qiiie ;
Kim, Suk Jun ;
Kar, Mahaprasad ;
Shafarman, William N. ;
Birkmire, Robert W. ;
Stach, Eric A. ;
Agrawal, Rakesh ;
Hillhouse, Hugh W. .
NANO LETTERS, 2008, 8 (09) :2982-2987
[5]
Large-scale growth of porous CuInS2 microspheres [J].
Hu, HM ;
Yang, BJ ;
Liu, XY ;
Zhang, R ;
Qian, YT .
INORGANIC CHEMISTRY COMMUNICATIONS, 2004, 7 (04) :563-565
[6]
Synthesis of nanocrystalline CuMS2 (M = In or Ga) through a solvothermal process [J].
Lu, QY ;
Hu, JQ ;
Tang, KB ;
Qian, YT ;
Zhou, GE ;
Liu, XM .
INORGANIC CHEMISTRY, 2000, 39 (07) :1606-+
[7]
Preparation and characterization of CuInSe2 nano-particles [J].
Lu, Wei-Lun ;
Fu, Yaw-Shyan ;
Tseng, Bae-Heng .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2008, 69 (2-3) :637-640
[8]
Synthesis of CuInS2, CuInSe2, and Cu(InxGa1-x)Se2 (CIGS) Nanocrystal "Inks" for Printable Photovoltaics [J].
Panthani, Matthew G. ;
Akhavan, Vahid ;
Goodfellow, Brian ;
Schmidtke, Johanna P. ;
Dunn, Lawrence ;
Dodabalapur, Ananth ;
Barbara, Paul F. ;
Korgel, Brian A. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (49) :16770-16777
[9]
Properties of 19.2% efficiency ZnO/CdS/CuInGaSe2 thin-film solar cells [J].
Ramanathan, K ;
Contreras, MA ;
Perkins, CL ;
Asher, S ;
Hasoon, FS ;
Keane, J ;
Young, D ;
Romero, M ;
Metzger, W ;
Noufi, R ;
Ward, J ;
Duda, A .
PROGRESS IN PHOTOVOLTAICS, 2003, 11 (04) :225-230
[10]
Synthesis and characterization of ternary CuInS2 nanorods via a hydrothermal route [J].
Xiao, JP ;
Xie, Y ;
Tang, R ;
Qian, YT .
JOURNAL OF SOLID STATE CHEMISTRY, 2001, 161 (02) :179-183