Nondipole resonant x-ray Raman spectroscopy: Polarized inelastic scattering at the K edge of Cl-2

被引：34

作者：

Mills, JD

Sheehy, JA

Ferrett, TA

Southworth, SH

Mayer, R

Lindle, DW

Langhoff, PW

机构：

[1] CARLETON COLL,DEPT CHEM,NORTHFIELD,MN 55057

[2] ARGONNE NATL LAB,DIV PHYS,ARGONNE,IL 60439

[3] JOHNS HOPKINS UNIV HOSP,DEPT RADIAT ONCOL,BALTIMORE,MD 21205

[4] UNIV NEVADA,DEPT CHEM,LAS VEGAS,NV 89154

[5] INDIANA UNIV,DEPT CHEM,BLOOMINGTON,IN 47405

来源：

PHYSICAL REVIEW LETTERS | 1997年 / 79卷 / 03期

关键词：

D O I：

10.1103/PhysRevLett.79.383

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Experimental and theoretical studies are reported on the inelastic (Raman) scattering of wavelength-selected polarized x rays from the K edge of gas-phase chlorine molecules. The polarized emission spectra exhibit prominent nondipole features consequent of phase variations of the incident and emitted radiation over molecular dimensions, as predicted by the Kramers-Heisenberg scattering formalism. Issues pursuant to the detection of core-hole localization by resonant Raman scattering from homonuclear diatomic molecules are critically examined.

引用

页码：383 / 386

页数：4

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