cis-[7,8-bis(diphenylphosphino)-7,8-dicarba-nido-undecaborato-P,P']dichloro-gold(III) chloroform solvate

被引:10
作者
Jones, PG [1 ]
Villacampa, MD [1 ]
Crespo, O [1 ]
Gimeno, MC [1 ]
Laguna, A [1 ]
机构
[1] UNIV ZARAGOZA,CSIC,INST CIENCIA MAT ARAGON,DEPT QUIM INORGAN,ZARAGOZA 50009,SPAIN
关键词
D O I
10.1107/S0108270197002059
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title compound. [AuCl2{C2B9H10(Ph2P)(2)}].CHCl3, contains the expected cis square-planar gold(III) units, with Au-P 2.306 and 2.296 (2), and Au-Cl 2.335 and 2.326 (2)Angstrom . The dicarbaundecaborate anion acts as a P. P'-bidentate ligand. The open B2C3 face contains one bridging (B-H-B)H atom.
引用
收藏
页码:570 / 572
页数:3
相关论文
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