Preparation of raspberry-like polypyrrole composites with applications in catalysis

被引：78

作者：

Yao, Tongjie ^{[1
]}

Wang, Chuanxi ^{[1
]}

Wu, Jie ^{[1
]}

Lin, Quan ^{[1
]}

Lv, Hui ^{[1
]}

Zhang, Kai ^{[1
]}

Yu, Kui ^{[2
]}

Yang, Bai ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Supramol Struct & Mat, Changchun 130012, Peoples R China

[2] Natl Res Council Canada, Steacie Inst Mol Sci, Ottawa, ON K1A 0R6, Canada

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 2009年 / 338卷 / 02期

关键词：

Polypyrrole (PPy); Silver (Ag); SiO2; Composites; Catalysis; SILVER NANOPARTICLES; METAL NANOPARTICLES; SILICA SPHERES; PARTICLES; POLYMERIZATION; NANOCOMPOSITES; NANOREACTOR; LATEXES;

D O I：

10.1016/j.jcis.2009.05.001

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Raspberry-like composites were prepared by coating the silver/polypyrrole core/shell composites onto the surface of silica spheres via oxidation polymerization of pyrrole monomer with [Ag(NH3)(2)](+) ions as oxidants. The whole process allowed the absence of stabilizers, which greatly improved the quality of the conducting polymer composites. The morphology of the resulting composites was investigated, which can be described as raspberry-like; also, the structure and composition of the composites were characterized in detail. A possible formation mechanism was proposed. The present synthetic strategy substantially extended the scope of metal/conducting polymer composite synthesis. The raspberry-like composites exhibited excellent catalytic properties in the reduction of methylene blue dye with the reducing agent of sodium borohydride. (C) 2009 Elsevier Inc. All rights reserved.

引用

页码：573 / 577

页数：5

共 28 条

[1] Shape-controlled synthesis of colloidal platinum nanoparticles [J].

Ahmadi, TS ;

Wang, ZL ;

Green, TC ;

Henglein, A ;

ElSayed, MA .

SCIENCE, 1996, 272 (5270) :1924-1926

[2] A surfactant-assisted preparation of well dispersed rhodium nanoparticles within the mesopores of AlSBA-15:: characterization and use in catalysis [J].

Boutros, Maya ;

Denicourt-Nowicki, Audrey ;

Roucoux, Alain ;

Gengembre, Leon ;

Beaunier, Patricia ;

Gedeon, Antoine ;

Launay, Franck .

CHEMICAL COMMUNICATIONS, 2008, (25) :2920-2922

[3] A simple and controlled method of preparing uniform Ag midnanoparticles on Tollens-soaked silica spheres [J].

Chen, ZM ;

Chen, X ;

Zheng, LL ;

Gang, T ;

Cui, TY ;

Zhang, K ;

Yang, B .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2005, 285 (01) :146-151

[4] Size dependence of Stober silica nanoparticle microchemistry [J].

Costa, CAR ;

Leite, CAP ;

Galembeck, F .

JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (20) :4747-4755

[5] Dendrimer-encapsulated metal nanoparticles: Synthesis, characterization, and applications to catalysis [J].

Crooks, RM ;

Zhao, MQ ;

Sun, L ;

Chechik, V ;

Yeung, LK .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (03) :181-190

[6] Interfacial polymerization of pyrrole and in situ synthesis of polypyrrole/silver nanocomposites [J].

Dallas, Panagiotis ;

Niarchos, Dimitrios ;

Vrbanic, Daniel ;

Boukos, Nicholaos ;

Pejovnik, Stane ;

Trapalis, Christos ;

Petridis, Dimitrios .

POLYMER, 2007, 48 (07) :2007-2013

[7] CHEMICAL SYNTHESIS AND DIELECTRIC CHARACTERIZATION IN MICROWAVE DOMAIN OF POLYPYRROLE LATEXES [J].

EPRON, F ;

HENRY, F ;

SAGNES, O .

MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1990, 35-6 :527-533

[8] Synthesis of functional polypyrrole/prussian blue and polypyrrole/Ag composite microtubes by using a reactive template [J].

Feng, Xiaomiao ;

Sun, Zhengzong ;

Hou, Wenhua ;

Zhu, Jun-Jie .

NANOTECHNOLOGY, 2007, 18 (19)

[9] One-step synthesis of polypyrrole-coated silver nanocomposite particles and their application as a coloured particulate emulsifier [J].

Fujii, Syuji ;

Aichi, Atsushi ;

Akamatsu, Kensuke ;

Nawafune, Hidemi ;

Nakamura, Yoshinobu .

JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (36) :3777-3779

[10] Synthesis and characterization of polypyrrole-coated sulfur-rich latex particles: New synthetic mimics for sulfur-based micrometeorites [J].

Fujii, Syuji ;

Armes, Steven P. ;

Jeans, Richard ;

Devonshire, Robin ;

Warren, Samantha ;

McArthur, Sally L. ;

Burchell, Mark J. ;

Postberg, Frank ;

Srama, Ralf .

CHEMISTRY OF MATERIALS, 2006, 18 (11) :2758-2765

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