Large optical power limiting induced by three-photon absorption of two stilbazolium-like dyes

被引:39
作者
Wang, DY
Zhan, CL
Chen, Y
Li, YJ
Lu, ZZ
Nie, YX
机构
[1] Chinese Acad Sci, Ctr Mol Sci, Lab Photochem, Beijing 100080, Peoples R China
[2] Chinese Acad Sci, Inst Phys, Lab Opt Phys, Beijing 100080, Peoples R China
基金
中国国家自然科学基金;
关键词
D O I
10.1016/S0009-2614(03)00004-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Three-photon absorption (3PA) of two stilbazolium-like dyes containing conjugated triple bridge (abbreviated as APAI and PPAI) has been determined by using a Q-switched Nd:YAG laser pumped with 35 ps pulses at 1064 nm in DMSO. Nonlinear absorption coefficients alpha(3) derived from 3PA fitting curves are 4.3 and 3.2 x 10(-21) cm(3)/W-2, respectively. Large optical power limiting induced by 3PA has also been demonstrated for both dyes. When the maximum incident irradiance reaches to 400 GW/cm(2), the limiting nonlinear transmissions T-lim can reach to 13 and 17% with maximum transmitted radiances of 17 and 44 GW/cm(2), respectively. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:621 / 626
页数:6
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