Unexpected and then rational synthesis of a new class of anionic phosphino-oxazoline ligands; structure and catalytic properties of a ruthenium complex

被引：18

作者：

Braunstein, P

Naud, F

Graiff, C

Tiripicchio, A

机构：

[1] Univ Strasbourg 1, Chim Coordinat Lab, CNRS, UMR 7513, F-67070 Strasbourg, France

[2] Univ Parma, Dipartimento Chim Gen & Inorgan, CNR, Ctr Studio Strutturist Diffrattometr, I-43100 Parma, Italy

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 11期

关键词：

D O I：

10.1039/b002515l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new class of anionic, hybrid chelating ligands is reported which contain a phosphine moiety covalently linked to an oxazoline of which the nitrogen atom formally carries a partly delocalized negative charge; the first metal complex, a ruthenium derivative, has been characterized by X-ray diffraction and shown to be active in catalytic transfer hydrogenation.

引用

页码：897 / 898

页数：2

共 30 条

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