Metallacumulenes: from vinylidenes to metal polycarbides

被引：95

作者：

Selegue, JP ^{[1
]}

机构：

[1] Univ Kentucky, Dept Chem, Lexington, KY 40506 USA

来源：

COORDINATION CHEMISTRY REVIEWS | 2004年 / 248卷 / 15-16期

基金：

美国国家科学基金会;

关键词：

metallacumulenes; vinylidenes; metal polycarbides; allenylidenes; metal carbides;

D O I：

10.1016/j.ccr.2004.08.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Metallacumulenes and carbide complexes exhibit diverse structures and modes of reactivity. This review presents an overview of work in the author's research group on vinylidene complexes of group 6 and 8 metals, allenylidene and butatrienylidene complexes of group 8 metals, and metal carbide, bicarbide and tricarbide complexes of group 6, 7 and 8 metals. (C) 2004 Elsevier B.V. All rights reserved.

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收藏

页码：1543 / 1563

页数：21

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