Toward a geochemical mass balance of major elements in Lake Qinghai, NE Tibetan Plateau: A significant role of atmospheric deposition

Sediments in Lake Qinghai archive important information about past environmental changes. In order to faithfully interpret the sediment records and constrain the elemental cycles, it is critical to trace various sources of sediments in the lake. The results show that the elemental input-output budgets are imbalanced for most major elements between riverine fluxes and mass accumulation rate (MAR) of Lake Qinghai sediments. A realistic model must include contributions of dry/wet atmospheric deposition that allow the major element mass balance for the lake to be defined. The budget estimation is based on mass balances of Si and Al, which are relatively immobile and carried to the lake via particulate forms. Estimated annual budget of dry atmospheric deposition is similar to 1.3 +/- 0.3 x 10(3) kt/a (accounting for similar to 65% of the total inputs) to the lake sediments. assuming local loess within the catchment as a candidate for dry atmospheric deposition to the lake. The resultant flux of 300 45 g/m(2)/a falls within the flux average of the desert area (400 g/m(2)/a) and the loess plateau (250 g/m(2)/a), consistent with the geographical setting of Lake Qinghai. The role of atmospheric deposition would be more significant if wet deposition via rainfall and snow were taken into account. This highlights the potential importance of dust as a significant source for sediment preservation flux for other catchments worldwide. The results also indicate that nearly all Ca input was preserved in the lake sediments under modem conditions, consistent with Ca(2+) Supersaturation of the lake water. (C) 2009 Elsevier Ltd. All rights reserved.