Sulflower: A new form of carbon sulfide

被引:179
作者
Chernichenko, Konstantin Yu. [1 ]
Sumerin, Viktor V. [1 ]
Shpanchenko, Roman V. [1 ]
Balenkova, Elizabeth S. [1 ]
Nenajdenko, Valentine G. [1 ]
机构
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia
关键词
annulation; oligothiophenes; polycycles; sulfur heterocycles; X-ray diffraction;
D O I
10.1002/anie.200602190
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) A sunny outlook: As the first fully heterocyclic circulene, sulflower opens the way to an unprecedented class of compounds that are both organic and inorganic. Sulflower is an oligothiophene as well as a new form of carbon sulfide that resembles a flower (see picture) and was synthesized in a short and effective approach. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:7367 / 7370
页数:4
相关论文
共 26 条
[1]  
[Anonymous], ANGEW CHEM
[2]   The versatile thiophene: An overview of recent research on thiophene-based materials [J].
Barbarella, G ;
Melucci, M ;
Sotgiu, G .
ADVANCED MATERIALS, 2005, 17 (13) :1581-1593
[3]   SYNTHESIS AND PROPERTIES OF SOME HETEROCIRCULENES [J].
DOPPER, JH ;
WYNBERG, H .
JOURNAL OF ORGANIC CHEMISTRY, 1975, 40 (13) :1957-1966
[4]   Persulfurated aromatic compounds [J].
Gingras, M ;
Raimundo, JM ;
Chabre, YM .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (11) :1686-1712
[5]  
Hirsch A., 2005, Fullerenes - Chemistry and Reactions
[6]  
Hoffmann R., 2003, HYLE-Int. J. Philos. Chem, V9, P7, DOI 10.1504/IJCRC.2016.076058
[7]  
HUMAYUN SMH, 2000, HETEROCYCLES, V52, P761
[8]   Triphenyleno[1,12-bcd:4,5-b′c′d′:8,9-b"c"d"]trithiophene:: the first bowl-shaped heteroaromatic [J].
Imamura, K ;
Takimiya, K ;
Aso, Y ;
Otsubo, T .
CHEMICAL COMMUNICATIONS, 1999, (18) :1859-1860
[9]   Poly(thiaheterohelicene): A stiff conjugated helical polymer comprised of fused benzothiophene rings [J].
Iwasaki, T ;
Kohinata, Y ;
Nishide, H .
ORGANIC LETTERS, 2005, 7 (05) :755-758
[10]   C-60 - BUCKMINSTERFULLERENE [J].
KROTO, HW ;
HEATH, JR ;
OBRIEN, SC ;
CURL, RF ;
SMALLEY, RE .
NATURE, 1985, 318 (6042) :162-163