Synthesis and structure of Pd(II) complexes of 1,2,3-triphenylguanidine

被引：11

作者：

Mincheva, N

Todorov, T

Angelova, O

Bailey, PJ

Mitewa, M ^{[1
]}

机构：

[1] Univ Sofia, Dept Chem, BU-1126 Sofia, Bulgaria

[2] Bulgarian Acad Sci, Cent Lab Mineral & Crystallog, Sofia 1000, Bulgaria

[3] Univ Edinburgh, Dept Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2000年 / 50卷 / 02期

关键词：

1,2,3-triphenylguanidine; Pd(II) complexes; X-ray structure;

D O I：

10.1080/00958970008054936

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The formation of two complexes by reaction of [PdCl4](2-) with 1,2,3-triphenylguanidine (PhNH)(2)C=NPh under different metal/ligand ratios has been observed and the structure of the complex [(1,2,3-triphenylguanidine)(2)PdCl2] has been determined by X-ray diffraction methods. The ligands are coordinated as neutral monodentate molecules to the metal centre through their imine nitrogen atoms. The second Pd(II) complex is [Pd(1,2,3-triphenylguanidine)(4)](2+) and was isolated by precipitation with ClO4-.

引用

页码：169 / 176

页数：8

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