Cycloaddition of C-60 fullerene to stable 2-RSO2-benzonitrile oxides

被引：16

作者：

Drozd, VN

Knyazev, VN

Stoyanovich, FM

Dolgushin, FM

Yanovsky, AI

机构：

[1] ND ZELINSKII INST ORGAN CHEM,MOSCOW 117913,RUSSIA

[2] AN NESMEYANOV ORGANOELEMENT CPDS INST,MOSCOW 117813,RUSSIA

来源：

RUSSIAN CHEMICAL BULLETIN | 1997年 / 46卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

C-60; fullerene; nitrile oxides; nitrile sulfides; interaction; 3+2] cycloaddition; isoxazolines; crystal structure;

D O I：

10.1007/BF02495359

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The interaction of stable 2-RSO2-benzonitrile oxides 1a-c (R = Ph, Bu-t, or PhMeN) with C-60 fullerene proceeds at the double (6,6)-bond of fullerene as the [3+2] cycloaddition to form the corresponding isoxazolines 2a-c. The molecular structure of compound 2b was established by X-ray structural analysis. The interaction of C-60 fullerene with 2-(5-methyl-4-nitrothiophene)carbonitrile sulfide, which was obtained by thermolysis of 5-(5'-methyl-4'-nitro-2'-thienyl)-1,3,4-oxathiazol-2-one, affords only unstable products.

引用

页码：113 / 121

页数：9

共 18 条

[1]

[Anonymous], [No title captured]

[2] Chiral derivatives of exo-metallofullerenes: Synthesis and X-ray study of solvate of platinumfullerene cluster with cyclooctene, eta(2)-C60Pt[(+)-DIOP]center dot C8H14 [J].