Fe-2(CO)(6)[In-C(SiMe3)(3)](3) with a trigonal-bipyramidal Fe2In3 cluster

被引：35

作者：

Uhl, W

Pohlmann, M

机构：

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 11期

关键词：

D O I：

10.1021/om970015e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In-4[C(SiMe3)(3)](4) (1) reacts with the tricarbonyliron cyclooctatetraene adduct to yield the dark red organoindium iron compound Fe-2(CO)(6)[In-C(SiMe3)(3)](3) (2), which is one of the very rare examples of a compound with two Fe(CO)(3) fragments symmetrically bridged by three main-group elements. 2 exhibits a trigonal-bipyramidal Fe2In3 molecular center with all indium atoms in equatorial positions. The Fe-ln bond lengths are as expected (258.2(2) pm), while the equatorial In-In distances of 364.8(1) pm indicate no significant bonding interaction.

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页码：2478 / 2480

页数：3

相关论文

共 46 条

[1] SYNTHESIS AND CHEMICAL CHARACTERIZATION OF SOME IN-FE HETERONUCLEAR CARBONYL-COMPOUNDS - CRYSTAL-STRUCTURE OF [NME3CH2PH]3[IN(FE(CO)4)3] AND [NET4]2[IN2BR4(MU-FE(CO)4)2] [J].

ALBANO, VG ;

CANE, M ;

IAPALUCCI, MC ;

LONGONI, G ;

MONARI, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 407 (02) :C9-C12

[2]

[Anonymous], 1977, ADV ORGANOMET CHEM

[3] THE CHEMISTRY OF TRICHLORO[TRIS(TRIMETHYLSILYL)METHYL] AND TRICHLORO[TRIS(DIMETHYLPHENYLSILYL)METHYL] COMPLEXES OF GALLIUM, INDIUM, AND THALLIUM - CRYSTAL AND MOLECULAR-STRUCTURES OF [LI(THF)2(MU-CL)2GACL-(C(SIME2PH)3)].THF, [LI(THF)3(MU-CL)INCL2(C(SIME3)3)], AND [((ME3SI)3C)IN(MU-CL)2(MU-FE(CO)4)IN(C(SIME3)3)] (THF = TETRAHYDROFURAN)L [J].

ATWOOD, JL ;

BOTT, SG ;

HITCHCOCK, PB ;

EABORN, C ;

SHARIFFUDIN, RS ;

SMITH, JD ;

SULLIVAN, AC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (04) :747-755

[4] SYNTHESIS AND CRYSTAL AND MOLECULAR-STRUCTURE OF IN(C5ME5) - AN APPARENT OCTAHEDRAL CLUSTER [J].

BEACHLEY, OT ;

CHURCHILL, MR ;

FETTINGER, JC ;

PAZIK, JC ;

VICTORIANO, L .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (15) :4666-4668

[5] SYNTHETIC, SPECTROSCOPIC AND STRUCTURAL STUDIES ON PHOSPHINE-STABILIZED [PPH(3),PH(2)PCH(2)PPH(2),PH(2)P(CH2)(4)PPH(2), (PH(2)P)C5H4N] MAIN-GROUP ELEMENT-IRON-SILICON CHAIN COMPLEXES [J].

BRAUNSTEIN, P ;

KNORR, M ;

STRAMPFER, M ;

DECIAN, A ;

FISCHER, J .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (02) :117-134

[6] A new In-4 cluster with short In-In bonds in trigonal-planar In(InTrip(2))(3) [J].

Brothers, PJ ;

Hubler, K ;

Hubler, U ;

Noll, BC ;

Olmstead, MM ;

Power, PP .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (20) :2355-2357

[7] SYNTHETIC AND STRUCTURAL STUDIES ON ORGANOTRANSITION-METAL INDIUM THIOCYANATE COMPLEXES [J].

CARMALT, CJ ;

NORMAN, NC ;

PEMBER, RF ;

FARRUGIA, LJ .

POLYHEDRON, 1995, 14 (03) :417-424

[8] STRUCTURES OF [(C2H5)4N]2[IN2FE6(CO)24] AND [(C2H5)4N][(2,2'-BIPYRIDINE)INFE2(CO)8] [J].

CASSIDY, JM ;

WHITMIRE, KH .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1990, 46 :1781-1785

[9] SYNTHETIC AND STRUCTURAL STUDIES ON ORGANOIRON INDIUM COMPLEXES [J].

CLARKSON, LM ;

NORMAN, NC ;

FARRUGIA, LJ .

ORGANOMETALLICS, 1991, 10 (05) :1286-1292

[10] ACCURATE DETERMINATION OF A CLASSIC STRUCTURE IN METAL-CARBONYL FIELD - NONACARBONYLDI-IRON [J].

COTTON, FA ;

TROUP, JM .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1974, (08) :800-802

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